Yes, it is a solution of different metals, all in the solid state.
Since the change in boiling point is directly proportional to the number of particles placed in the solution, B must form three times as many particles as A.
For a water solution that is 1 m in sugar, which dissolves into molecules and only provides one particle:
ΔTb = Kb m = (0.52 °C/m)(1.0 m) = 0.52 °CFor a water solution that is 1 m in MgCl2, which dissolves into ions and provides three particles:
ΔTb = Kb m = (0.52 °C/m)(3.0 m) = 1.56 °C
CaCl2 provides three particles while NaCl only provides two.
Antifreeze mixed with water will have a lower freezing point than either pure water or pure antifreeze due to the particles of the one that are dissolved in the other.
It might make it taste better and maybe keep it from sticking as much, but it would also raise the boiling point, allowing the water to get hotter, and cooking the spagetti faster.
The popsicles have particles dissolved in them which lowers the freezing point.